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Beilstein J. Org. Chem. 2016, 12, 172–178, doi:10.3762/bjoc.12.19
Graphical Abstract
Scheme 1: Dual-gold-catalysed hydrophenoxylation of alkynes.
Scheme 2: Exploring the functional group tolerance. Reaction conditions: 1a (0.50 mmol, 1 equiv), 2a–o (0.55 ...
Scheme 3: Hydrophenoxylation using polyphenols. Reaction conditions: 1a (1 mmol, 2 equiv), 2p–s (0.50 mmol, 1...
Scheme 4: Hydrophenoxylation of (un)symmetrical alkynes. Reaction conditions: 1b–k (0.50 mmol, 1 equiv), 2t (...
Scheme 5: Regioselective hydrophenoxylation of unsymmetrical alkynes. Reaction conditions: 1l–p (1 equiv), 2a...
Beilstein J. Org. Chem. 2013, 9, 2216–2223, doi:10.3762/bjoc.9.260
Scheme 1: Straightforward synthesis of organogold complexes via deprotonation reactions, using 1.
Scheme 2: Scope of the reaction between 1 and several (hetero)aromatic amines. Reaction conditions: 1 (1 equi...
Figure 1: X-ray crystal structures of complexes 2, 3, 7, 8, 10, 11 and 12. Hydrogen atoms are omitted for cla...
Figure 2: Selected examples of gold–NHC amide complexes under UV light (λ = 366 nm).
Figure 3: Excitation (blue) and emission (pink) data for complex 3, bearing a 2-pyridine ligand (see inset).
Figure 4: (a) LUMO, (b) HOMO and (c) HOMO-1 of complex 3.